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Copper
Copper is beginning to be used because it allows the
microcircuits to go at higher speeds. The advantage copper has over aluminum is
that copper has less resistance and therefore allows electrons to flow faster.
This reduces the chip interconnect delays and results in increased speed for
semiconductor devices. The use of copper also reduces power consumption. Copper
may prove to be a necessity as transistor sizes go to 0.18-micron and beyond. As
the circuit size is decreased, the signal-current densities increase and more
heat is generated. Copper can support much higher current densities than
aluminum because it has a higher melting point. In addition, copper is more
reliable than aluminum under the same current densities. Another problem that
arises with smaller geometries is crosstalk (the leakage of electrons). Because
copper is a better conductor than aluminum it is less likely to leak electrons.
Using better dielectric materials with lower dielectric constant (k) values can
also alleviate crosstalk. They’re some issues with copper that need
consideration:
a. Copper is
difficult to etch. Manufacturers have to change their deposition and etch steps.
The industry is adapting the Damascene process in which the interconnect lines
and vias are etched to remove the dielectric materials instead of the metal,
whereas with aluminum the metal is etched. This switch to dielectric etch from
metal etch has created new requirements for etching tools and technology.
b. The need
to deposit the damascene barrier and seed layers before copper deposition is a
problem. The purpose of the barrier layer is to prevent the copper from
diffusing into the dielectric material and destroying the transistors. The
Damascene process starts with a layer of dielectric material that is etched by
photolithography to produce the circuit pattern. A barrier layer (typically a
few hundred angstroms of refractory titanium or tungsten-nitride) is applied to
the etched pattern. On the barrier layer, a very thin seed layer is deposited by
physical-vapor deposition to serve as a “primer” on which the copper is laid.
Since the few-hundred-angstrom barrier layer is deposited in the circuitry prior
to the copper, the barrier layer reduces the height and width of the copper
trace; therefore reducing the resulting overall thickness of the copper
interconnect. The thinner the copper interconnect is, the higher the resistivity
will be and at very fine geometries the barrier layer can have a dramatic impact
on the speed of the circuitry.
c. Depositing
microscopic copper interconnects on a microcircuit is very difficult. The
problem lies with the high aspect ratios presented by the 0.25 micron and below
vias and holes that can have depths as great as 1.0 micron. It is hard to
completely fill in the etched pattern in the dielectric and this can result in
voids and small cracks in the copper leading to opens in the microcircuit.
d. Current
processes for copper deposition are chemical-vapor-deposition (CVD) and
electrochemical plating; they both have problems with the very fine pitch
geometry.
e. Copper
does not mix well with current dielectric materials used for aluminum. Copper
can diffuse quickly through the insulating oxides (dielectrics) and into the
silicon, destroying the transistors (hence, the use of the barrier layer
mentioned above).
Signal Propagation
Speeding up signal propagation through the
microcircuit can be accomplished by using a dielectric material with a low k.
The lower k will speed up the signal by decreasing the charge buildup between
the conductive lines. Some issues with new dielectrics that need consideration
are detailed below:
a. The shift
to 0.18-µm and smaller process geometries and copper interconnects places new
requirements on dielectric materials used in fabrication. With geometries over
0.5µm, silicon dioxide, with a k of about 4, was used successfully to isolate
layers of metals. As linewidths have gotten smaller, the use of silicon dioxide
is no longer feasible because its relatively high k value creates excessive
charge build-up on the metal lines and slows the signal propagation.
b. The
capacitance increases as k increases, and the capacitance increases as the
linewidths get smaller. It is important to use low-k dielectrics with small
geometry microcircuits. Wire delay increases as a percentage of total delay in
the smaller geometries. Manufacturers are using dielectric materials with
constants of between 3.0 and 4.0 for their 0.18µm processes. To go to 0.15µm and
below, dielectric constants will need to be limited to 3.0 or less.
c. An ideal
low-k material is one that offers a low dielectric constant and has similar
properties as silicon-dioxide, such as low leakage, low thermal coefficient of
expansion (<10 ppm/C), high dielectric break-down voltage (2-3 MV/cm), low
film stress, low water absorption, high cracking resistance, and adhesion to
other materials.
d. Another
critical factor is the ability to integrate the low-k materials easily into the
manufacturing process. Low-k materials have been difficult and expensive to
integrate into production lines and are poor thermal conductors.
e. Making the
material porous can lower the dielectric constant of organic polymers. For
example, a polymer with a k value of 2.65 can be modified to have a k value of
just about 2.0 by putting 20% porosity in the
polymer.